Chemists develop laboratory method to generate atomic hydrogen
Researchers have overcome a century-long barrier by making isolated hydrogen atoms accessible in the chemistry lab for synthetic work.
What to know
- Isolated hydrogen atoms—the simplest and most reactive chemical species—have been inaccessible to synthetic chemists for over a century despite being the most abundant element in the universe.
- Early methods by Langmuir (1912, thermal) and Franck (1922, mercury photosensitization) generated atomic hydrogen but were impractical for routine chemistry due to extreme conditions or toxic reagents.
- Researchers have now developed a laboratory method that makes atomic hydrogen accessible as a practical synthetic reagent for building new compounds.
“This single, unpaired electron makes it what chemists call a radical; the most fundamental reactive species in all of chemistry.”
The Conversation · The Conversation article
Irving Langmuir American chemist, General ElectricJames Franck German-American physicistRobert Crabtree Chemist
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The hydrogen atom: the universe built almost everything with it. Synthetic chemists are only just learning to use it in the lab.
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background
Franck discovers mercury photosensitization method for splitting hydrogen — German-American physicist James Franck discovers that mercury atoms exposed to ultraviolet light at 254 nanometres can absorb energy and transfer it to hydrogen molecules, breaking them apart into atoms. The process, called mercury photosensitization, works but requires toxic mercury vapor and specialized UV lamps.
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background
Langmuir first generates atomic hydrogen by heating over tungsten — Irving Langmuir, an American chemist at General Electric, becomes the first scientist to temporarily create atomic hydrogen by heating molecular hydrogen over a tungsten filament to above 1,700°C. The recombination of atoms at cooler surfaces releases enormous energy, producing temperatures of 3,400°C to 4,000°C—enough to weld tungsten, making it an early industrial welding process.
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first by Mastodon, 10d ago · also The Conversation